High-Pressure Phase Behavior of Polycaprolactone, Carbon Dioxide, and Dichloromethane Ternary Mixture Systems

High-pressure polymeric phases of carbon dioxide.

Understanding the structural transformations of solid CO(2) from a molecular solid characterized by weak intermolecular bonding to a 3-dimensional network solid at high pressure has challenged researchers for the past decade. We employ the recently developed metadynamics method combined with ab initio calculations to provide fundamental insight into recent experimental reports on carbon dioxide...

Sterilization using high-pressure carbon dioxide

Sterilization using high-pressure carbon dioxide Jian Zhang a, Thomas A. Davis a, Michael A. Matthews a,∗, Michael J. Drews b, Martine LaBerge c, Yuehuei H. An d a Department of Chemical Engineering, University of South Carolina, Columbia, SC 29208, USA b School of Materials Science and Engineering, Clemson University, Clemson, SC 29634, USA c Department of Bioengineering, Clemson University, C...

Molecular carbon dioxide at high pressure and high temperature

Group Contribution Method for Predicting the Phase Behavior of Binary Mixtures Containing Carbon Dioxide

A New Molecular Solid Phase of Carbon Dioxide at High Pressure and Temperature